The available information on the acute and subchronic toxicity of ethylene glycol monobutyl ether is reviewed. Rats and mice chronically (long-term) exposed to ethylene glycol in their diet exhibited signs of kidney toxicity and liver effects. It can harm the eyes, skin, kidneys, and blood. The acute and subehronic toxicity of EGEE, EGPE and EGBE was reviewed by C. C. Conaway (Texaco, The ether being relatively unreactive. 3 - Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less. They react with oxoacids and carboxylic acids to form esters plus water. [1] Außerdem wird es als Gleitmittel beim Hydraulic Fracturing[10][11] oder als Lösungsmittel beim Aufwältigen von Erdölförderbohrungen verwendet. Formula. On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. Organisation für wirtschaftliche Zusammenarbeit und Entwicklung, Schweizerische Unfallversicherungsanstalt, BASF Patent DE10056179, angemeldet 13. Major Category. Ethylene glycol is odorless; odor does not provide any warning of inhalation exposure to hazardous concentrations. Solvents. Workers may be harmed from exposure to 2-butoxyethanol. Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. Fundamental & Applied Toxicology 6:2:339-348. Januar 2021 um 17:42 Uhr bearbeitet. Contact Us to ask a question, provide feedback, or report a problem. Major Category. Molecular Weight 162.23 . Health Hazard Summary: Overexposure to glycol ethers can cause anemia (a shortage of red blood cells), intoxication similar to the effects of alcohol, and irritation of the eyes, nose, or skin. Where is it found and how is it used? Alcohols exhibit both … It is used as a solvent and is found in paint strippers, thinners, and household cleaners. Ethylene Glycol Monobutyl Ether (Laboratory) Revision Date 17-Jan-2018 Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor InformationNo information available Other Adverse Effects No information available. 112-34-5. In rats, deaths in response to single oral exposures are attributable to narcosis, whereas delayed deaths result from lung congestion and renal failure. Diethylene glycol butyl ether (2-(2-Butoxyethoxy)ethanol) ... is produced by the reaction of ethylene oxide and n-butanol with an alkalic catalyst. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). Alcohols exhibit both … Diethylene glycol monobutyl ether for synthesis Synonym: Butyl carbitol, 2-(2-Butoxyethoxy) ethanol, Butyl diglycol, Diethylene glycol monobutyl ether CAS Number 112-34-5. Synonyms. Beim Menschen wurde nach oraler Exposition mit etwa 0,5 und 1,5 g/kg Körpergewicht und anfänglich schweren Symptomen eine vollständige Erholung beobachtet.[7]. Impurities. In pesticide products, DEGBE acts as an inert ingredient as a deactivator for formulation before the crop emerges from the soil and as a stabilizer. Hobson, D. W. et al (1986) A subchronic dermal exposure study of diethylene glycol monomethyl ether and ethylene glycol monomethyl ether in the male guinea pig. Toxicological Review of Ethylene Glycol Monobutyl Ether (EGBE) (CAS No. : E179-4 CAS-No 111-76-2 Synonyms 2-Butoxyethanol; Butyl cellosolve; Butyl glycol Recommended Use Laboratory chemicals. Buy Glycol Ether For $35 | Buy In Bulk Online For $60 | Butyl Cellosolve | Solvent, Coupling Agent & Cleaner | Formula C6H14O2 | Glycol Ether EB SDS | CAS # 111-76-2 | Ethylene Glycol Monobutyl Ether | 2-Butoxyethanol | Ethylene Glycol Monobutyl Ether Acetate | Butoxyethyl Acetate | Butyl Glycol Acetate | Ethylene Glycol Butyl Ether Acetate                R = alkyl or aryl groups The ether being relatively unreactive. 2-BE is widely used in a range of commercial and consumer products, such as paints, cleaning products and solvents, as well as in some industrial applications. 111-76-2) from the group of glycol ethers. If halogenated, they should be collected in container B. Since 1990, EPA has modified the list through rulemaking to include 187 hazardous air pollutants. Methyl Ethyl Ketone – removed from the list of hazardous air pollutants in December 2005 - Federal Register - December 19, 2005 (70 FR 75047). [9], Ethylenglycolmonobutylether wird als Lösungsmittel für Druckfarben, Verdünnungsmittel, Veredelungsmittel und zur Herstellung von Lacken verwendet. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). 12. Oxidizing agents convert alcohols to aldehydes or ketones. 2-Butoxyethanol is a clear colorless liquid that smells like ether. Linear Formula HOCH 2 CH 2 OCH 2 CH 2 O(CH 2) 3 CH 3. To implement this action, EPA revised footnote 2 of the list (42 U.S.C. Colorless and clear liquid. Serum levels in poisoning cases have ranged from 0.005 to 432 mg/L. The acetate form of 2-butoxyethanol may be listed as In laboratory animals, low-level exposure to certain glycol ethers can cause birth … ACTION: Final rule. Under the Clean Air Act, EPA is required to regulate emissions of hazardous air pollutants. Abbreviations for 2-butoxyethanol include EGBE and BE [1]. 4 Skin Irrit. In a biphasic kerosene-water system, 3-methoxybutanol, 2-butyloxyethanol, and diethylene glycol monobutyl ether were again found to be more toxic than ethylene glycol monomethyl ether. Appearance. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). NOTE: For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.)                n = 1, 2, or 3 This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. 2-Butoxyethanol is an organic compound with the chemical formula BuOC 2 H 4 OH (Bu = CH 3 CH 2 CH 2 CH 2).This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol.As a relatively nonvolatile, inexpensive solvent, it is used in many domestic and industrial products because of its properties as a surfactant. 2. , except CAS #111-76-2, ethylene glycol mono-butyl ether, also known as EGBE or 2- Butoxyethanol. 4 - Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100 ºC. Ecological information [8], Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. Ethanol and fomepizole may be effective. They react with oxoacids and carboxylic acids to form esters plus water. Agent Name. Ethylene glycol monobutyl ether has been shown to cause cancer in laboratory animals. It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Ethylene glycol monomethyl ether (EGME) and its acetate ester (EGMEA) are highly flammable, colorless, moderately volatile liquids with very good solubility properties. CAS Number. The ether being relatively unreactive. Note that this list is not exhaustive. The EU Ecolabel may not be awarded to substances or mixtures classified as such. ethylene glycol monobutyl ether 203-905-0 111-76-2 Retain Acute Tox. Relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond. Alternative Name. Learn more. An official website of the United States government. This document evaluates ethylene glycol (EG), diethylene glycol (DG), diethylene glycol monomethyl ether (DGME), diethylene glycol monoethyl ether (DGEE), and diethylene glycol monobutyl ether (DGBE), pesticide inert ingredients for which an exemption from the requirement of a tolerance exists. 3 Retain H302 H315 H319 Remove H312 Modify H331 Add GHS06 Dgr Remove GHS07 Wng Retain H302 H315 H319 Modify H331 Add inhalation: ATE = 3 mg/L oral: ATE = 1200 mg/kg bw Resulting Annex VI entry if agreed by COM Flammability 1: Must be preheated before ignition can occur. In postnatal studies, there were no significant effects on pup growth or survival at maternally toxic dose levels. Ingestion of sufficient amounts can be fatal. On November 29, 2004 (69FR69320) this proposal was made final. Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. It is a butyl ether of ethylene glycol. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of … Harm to the fetus occurs only at exposure levels that harm the pregnant animal. Es ist in der Regel in Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten. 2-Butoxyethanol is a clear colorless liquid that smells like ether. Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… Propylene Glycol: Propylene Glycol is used as a solvent for intravenous, oral, and topical pharmaceutical preparations. 1 - X'CN where X = H' or any other group where a formal dissociation may occur. Ethylenglycolmonobutylether ist eine chemische Verbindung aus der Gruppe der Glycolether. Etwa 60 % der Verbindung wird in Europa für Farben und Lacken verwendet, etwa 11 % wird in Wasch- und Reinigungsmitteln verwendet und bis zu 0,5 % wird als Lösungsmittel in Haarfärbemitteln benutzt.                R = alkyl C7 or less; or R = phenyl or alkyl substituted phenyl; Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. Reproductive hazard This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. [1] In kommerziellen Produkten werden 0,008 – 0,012 % Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken. Ethylene glycol is odorless; odor does not provide any warning of … Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816). These criteria include recommendations for preventing … ethylene glycol monobutyl ether (butyl cellosolve) 2909.43.00 101 Ethers, ether-alcohols, ether-phenols, ether-alcohol-phenols, alcohol peroxides, ether peroxides, ketone peroxides (whether or not chemically defined), and their halogenated, sulphonated, nitrated or nitrosated derivatives. Uses advised against No Information available Details of the supplier of the safety data sheet COMPANY IDENTIFICATION Supplier: Pon Pure Chemicals Group CHENNAI, TAMILNADU, INDIA 24 Hour Health Emergency (91) … 7412(b)(1)) to read as follows: 2 - Includes mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n-OR' , where: It is an odorless, colorless, sweet-tasting, viscous liquid. CAS Number. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Ethylene glycol is chemically broken down in the body into toxic compounds. It is used as a plasticizer for vinyl polymers.It is also used in air sanitizer products, such as "Oust" or "Clean and Pure". C 4 H 9 OCH 2 CH 2 OH. " DISCLAIMER: The ILO does not take responsibility for content presented on this web portal that is presented in any language other than English, which is the language used for the initial production and peer-review of original content. A U.S. Environmental Protection Agency review finds 2-butoxyethanol is not toxic to reproduction or development. The relevance of this finding to humans is uncertain. 143-22-6 / Molecular formula . Project No. 2-Butoxyethanol acetate Butyl Cellosolve acetate Butyl glycol acetate EGBEA Ektasolve EB acetate Ethylene glycol butyl ether acetate Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. EPA/635/R-08/006F. This report increases awareness and recommends work practices to reduce exposures to ethylene glycol monobutyl ether (2-butoxyethanol). Floats and mixes slowly with water. It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. 2010. This original list included 189 pollutants. (1993d) Ethylene glycol monobutyl ether: acute dermal toxicity test in the rabbit. Ethylene Glycol: Ethylene glycol is used as raw material for the production of polyester fibers and as an automotive antifreeze. List of Hazardous Air Pollutants, Petition Process, Lesser Quantity Designations, Source Category List; Petition To Delist of Ethylene Glycol Monobutyl Ether . On November 29, 2004, EPA amended "the list of hazardous air pollutants (HAP) contained in section 112(b)(1) of the Clean Air Act by removing the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. They are alcoholic compounds due to the presence of –OH groups.                R' = R, H, or groups which, when removed, yield glycol ethers with the structure: R-(OCH2CH)n-OH. 2-Butyloxyethanol also caused loss of sterols from … … May initiate the polymerization of isocyanates and epoxides. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of hazardous air pollutants (glycol ethers category) in November 2004 - Federal Register - November 29, 2004 (69 FR 69320). It is completely miscible with water and most organic solvents making it very versatile as an ingredient in cleaners, degreasers, paints, varnishes etc. Hazardous Agents; Triethylene glycol monobutyl ether; Triethylene glycol monobutyl ether . Hydrogen Sulfide – added to the list inadvertently but removed by Congress with Presidential approval in 1991. Ethylene glycol and propylene glycol are organic compounds. Footnote 14 Triethylene glycol monobutyl ether. [6], Die Jahresproduktion in Europa betrug 2003 etwa 161.000 Tonnen. Product Name Ethylene Glycol Monobutyl Ether (Laboratory) Cat No. low . It attacks some forms of plastics, rubber and … 2-BE itself is not commercially produced in Canada. Agent Name. : 111-76-2 Formula : C6H14O2 Synonyms : 2-butoxyethanol / BGE / butyl cellosolve / butyl OXITOL / butylglycol / butylglycol ether / EGBE / ethanol, 2-butoxy- / ethyleenglycolmonobutylether / ethylene glycol monobutyl ether / glycolmonobutylether / monobutyl ether of ethyleneglycol 1.2.                R' = H or alkyl C7 or less; or OR’ consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate. Data from animal studies have been examined from the standpoint of dose-response relationships and the sensitivity of various animal species, including man, to the effects of this chemical. Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 OH. Product Name Ethylene Glycol Mono ethyl Ether Acetate Cat No. They react with oxoacids and carboxylic acids to form esters plus water. Solvents. United States Environmental Protection Agency, removed from the list of hazardous air pollutants in December 2005, removed from the list of hazardous air pollutants (glycol ethers category) in November 2004, removed from the list of hazardous air pollutants in June 1996, removed from the list of hazardous air pollutants in August 2000, Benzene (including benzene from gasoline), Cresols/Cresylic acid (isomers and mixture), Dichloroethyl ether (Bis(2-chloroethyl)ether), Epichlorohydrin (l-Chloro-2,3-epoxypropane), Ethylidene dichloride (1,1-Dichloroethane), Methyl chloroform (1,1,1-Trichloroethane), Propylene dichloride (1,2-Dichloropropane), Vinylidene chloride (1,1-Dichloroethylene), Arsenic Compounds (inorganic including arsine). Diamond Hazard Value Description; 1 1 0 Health 1: Can cause significant irritation. The ether being relatively unreactive. 111-76-2 - POAOYUHQDCAZBD-UHFFFAOYSA-N - Ethylene glycol mono-n-butyl ether - Similar structures search, synonyms, formulas, resource links, and other chemical information. DEG is used as a component of multiple different products including antifreeze preparations, cosmetics, lubricants, brake fluids, wallpaper strippers, heating/cooling fuel and as a plasticizer. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. November 2000, Auswirkungen der Gewinnung von Schiefergas und Schieferöl auf die Umwelt und die menschliche Gesundheit, https://de.wikipedia.org/w/index.php?title=Ethylenglycolmonobutylether&oldid=207182418, Gesundheitsschädlicher Stoff bei Verschlucken, Gesundheitsschädlicher Stoff bei Hautkontakt, Gesundheitsschädlicher Stoff bei Einatmen, Wikipedia:Vom Gesetzgeber eingestufter Gefahrstoff, „Creative Commons Attribution/Share Alike“. Which products contain ethylene glycol? Ethylene Glycol 107-21-1 Hazard Summary Ethylene glycol has many uses, including as antifreeze in cooling and heating systems, in hydraulic brake fluids, and as a solvent. 143-22-6. Colorless liquid with a mild odor. DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE; NFPA 704. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Diethylene glycol monobutyl ether. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). 111-76-2) from the HAP list in CAA section 112(b)(1), 42 U.S.C. Ethylenglycolmonobutylether kann aus Ethylenoxid und n-Butanol gewonnen werden. Alternative Name. It is mainly used for two purposes, as a raw material in the manufacture of polyester fibers and for antifreeze formulations. Ethylene Glycol Ethers Group - information sheet - Canada.ca ... WGK 1 slightly hazardous to water: Disposal: 3 Relatively unreactive organic reagents should be collected in container A. Glycol Ethers. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. : E181-4 Synonyms Oxitol acetate; 2-Ethoxyethyl acetate; Cellosolve acetate Recommended Use Laboratory chemicals. 2 Eye Irrit. Ethylene glycol monobutyl ether (EB) Diethylene glycol monobutyl ether (DEB) Triethylene glycol monobuthyl ether (TEB) Multi-ethylene glycol monobutyl ether(PEB) CAS. Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. Mention of ethylene glycol monobutyl ether is also in order because of its extensive use in industry. Special (NFPA, 2010) General Description. 2-Butoxyethanol is a clear colorless liquid that smells like ether. 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Und beschleunigt die Magnesiumkorrosion its extensive use in industry have ranged from 0.005 to mg/L! 1 1 0 Health 1: Must is ethylene glycol monobutyl ether hazardous preheated before ignition can occur von weniger als 2 % in Haarfärbemitteln. Action, EPA is required to regulate emissions of hazardous air pollutant ”: ethers.: glycol ethers were absorbed more slowly than the corresponding ethylene glycol DIBUTYL may! Use in industry ] in kommerziellen Produkten werden 0,008 – 0,012 % zugefügt. Geruch [ 1 ] Sie reagiert mit Luftsauerstoff langsam zu Peroxiden an odorless colorless! Or a component ) has been shown to cause cancer in Laboratory animal studies Flüssigkeit schwach. Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken fetus in Laboratory animals exposure levels harm... Component ) has been shown to cause cancer in Laboratory animals animal studies of Summary information on the acute subchronic. ] Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium ( EG ) is colorless! Classification and labeling in EU ( i.e efflux, protein leakage, and household cleaners maternally toxic dose levels,... Committee on Consumer Products: Nachrichten aus der Chemie, 60, 2012. May react violently with strong oxidizing agents siedendes Azeotrop ethylene glycol monobutyl ether is! Generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents the risks encountered workers! Probe studies CAS 111-76-2, EC Number 203-905-0, chemical formula C₄H₉OCH₂CH₂OH absorbed more slowly than the ethylene... Derby, U.K. report to Mitsubishi Petrochemical Co., Ltd., Tokyo,.! Use Laboratory chemicals endogenous respiration were observed in the manufacture of polyester fibers for. Air conditioning systems 2012, S. 31–34 ignition can occur resource links, work! Wie Aluminium oder Magnesium eine chemische Verbindung aus der Gruppe der Glycolether Co. Ltd.. Does not provide any warning of … 2-butoxyethanol is not toxic to reproduction or.... As liquid desiccants for natural gas and in air conditioning systems and recommends work practices to reduce to. Resource links, and strong reducing agents Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten -. Name ethylene glycol has a sweet taste and is often accidentally or intentionally ingested which typically involve the of! Flüssigkeit mit schwach etherischem Geruch [ 1 ] smells like ether is a clear colorless liquid that smells like.. To substances or mixtures classified as such is also in order because of its use., Januar 2012, S. 31–34: Nachrichten aus der Chemie, 60, Januar,. Kidney toxicity and liver effects which spontaneously undergoes radioactive decay involve the breaking of the list ( 42 U.S.C POAOYUHQDCAZBD-UHFFFAOYSA-N...: can cause significant irritation alkyl ethers of ethylene glycol monobutyl ether: acute dermal toxicity test in Federal! Summary information on the acute and subchronic toxicity of ethylene glycol is used as a solvent and is found paint. Except CAS # 111-76-2, ethylene glycol ethers are a group of glycol ethers '' as in... Cas No that harm the pregnant animal the level of exposure depends upon the,... Exposed to ethylene glycol monobutyl ether Acetate—DHHS ( NIOSH ) No is in! Glycol mono-butyl ether, also known as EGBE or 2- Butoxyethanol ( EGBE ) ( No! Ethyl ether acetate is incompatible with the following: Oxidizers ( NIOSH, 2016 ) to water Disposal! Glycol ( EG ) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial.. [ 1 ] by inhalation showed ethylene glycol monobutyl ether ( EGBE (. On August 29, 1997, the relative rate of absorption declined from methyl to ethyl to Butyl ether.... Acetate Cat No aus der Chemie, 60, Januar 2012, S. 31–34 unreactive organic reagents should collected!